Which explains why Italian fashion giants Dolce & Gabbana snapped up the pair for a television commercial which was shot in the West Village, New York on Saturday.
Oscar winning director Martin Scorsese directed the action with Matthew and Scarlett pretending to be lovers during the shoot as a summer shower fell on the Big Apple.
Lost In Translation beauty Scarlett, 28, wore a stunning black crochet style lace long sleeved dress with sling-back heels and a black leather bag.
With flawless make-up and her blonde hair in an 'up-do' the stunning actress looked camera ready as she strolled beside handsome Matthew.
The 43-year-old actor looked dashing in a dark suit, crisp white shirt and black tie, with his hair slicked over to the side.
At one point assistants on the set had to use umbrellas to protect the A-list stars from getting soaked as the rain continued to fall on the set.
Both actors waited patiently for the weather to turn and when it did they played the part of romantic lovers as they strolled through the empty New York streets.
This isn't the first time the Goodfellas filmmaker has leant his name to advertisements -- he's long been a spokesman for American Express credit cards, even starring in many of the shorts.
Back in April Matthew and Scarlett teamed-up with the fashion giants for a fashion shoot on a beach in Malibu, California.
The two actors are obviously a favourite with the luxury brand as they have also been used to promote their perfume range 'The One' too.
In real life Matthew is happily married to former Brazilian model Camila Alves with the pair now having three children - Livingston, three months, Vida, 3 and Levi, 5.
The brunette beauty even paid a visit to her husband on the set, looking like she could easily step into Scarlett's role in a red peplum dress and matching black shawl and heels.
While Avengers beauty Scarlett is dating Frenchman Romain Dauriac. Joelle's Picks
Photos courtesy:Splash News Startrak photos